Effects of the reaction cavity on metastable optical excitation in ruthenium-sulfur dioxide complexes
نویسندگان
چکیده
منابع مشابه
Light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes.
The irradiation of ruthenium-sulfur dioxide complexes of general formula trans-[Ru(II)(NH(3))(4)(SO(2))X]Y with laser light at low temperature results in linkage isomerization of SO(2), starting with eta(1)-planar S-bound to eta(2)-side S,O-bound SO(2). The solid-state photoreaction proceeds with retention of sample crystallinity. Following work on trans-[Ru(NH(3))(4)Cl(eta(1)-SO(2))]Cl and tra...
متن کاملThe first photocrystallographic evidence for light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes.
Light-induced metastable linkage isomers of trans-[Ru(NH(3))(4)Cl(SO(2))]Cl and trans-[Ru(NH(3))(4)(H(2)O)(SO(2))](C(6)H(5)SO(3))(2) have been identified for the first time using photocrystallographic methods. In both linkage isomers the SO(2) ligand is side bound, but the Ru-O and Ru-S distances are considerably longer and almost equal in the trans-H(2)O isomer. DFT calculations confirm that b...
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2010
ISSN: 1098-0121,1550-235X
DOI: 10.1103/physrevb.82.155118